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Organic Peroxide Formers Storage and Handling Checklist  
 
Summary: Storage and handling of peroxide-forming materials requires careful labeling, observation, and testing to guard against and recognize the formation of dangerous organic peroxides. If your inventory includes chemicals that form peroxides, follow these guidelines.
What to do How to do it
Identify organic peroxide formers in your chemical inventory.
Store chemicals safely.
Label peroxide formers. Chemicals that degrade over time require extra labeling information.
  • Tag peroxide formers to make them easily identifiable.
  • Make sure chemical labels include the following additional required information:
    • Date received
    • Date opened
    • Date tested (contact the chemical safety officer for testing methods and applicability)
    Note: Synthesized material or other laboratory specific operations may present unique circumstances. Contact the chemical safety officer if you have questions.
  • Label refillable dispensing containers holding peroxide formers with the fill date.
Follow these steps if you discover expired or old peroxide-forming materials. Be aware of the passage of time when peroxide formers are in your chemical inventory.
  • Review your inventory frequently (including refillable containers) to prevent peroxide formers from reaching unsafe conditions.
  • If you find a peroxide-forming material past its expiration date, or more than 1 year past its receipt date, DO NOT OPEN OR MOVE the container.
    • Request a hazardous waste collection promptly.
    • Label the container to avoid possible inadvertent use until Environment, Health & Safety (EH&S) collects it.
  • If the material is very old or shows evidence of conversion to a hazardous status (crystalline materials in or under the cap of ethers, for example), DO NOT MOVE THE CONTAINER.
    • Contact EH&S immediately at (858) 534-3660 or 534-2753.


Need an expert? Contact an EH&S Research Assistance Program specialist.


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Last reviewed/updated on Sep. 15, 2008 (see more info)
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