Flammable and combustible liquids present a danger of personal injury and property damage, so strict storage requirements are both essential and required by law.
Facts about flammable and combustible liquids:
- Flammable and combustible liquids ignite easily and burn with extreme rapidity.
- Flammability is determined by the flash point of a material.
- Flash point is the minimum temperature at which a liquid forms a vapor above its surface in sufficient concentration that it can be ignited.
- Flammable liquids have a flash point of less than 100°F. Liquids with lower flash points ignite easier.
- Combustible liquids have a flashpoint at or above 100°F.
- The vapor burns, not the liquid itself. The rate at which a liquid produces flammable vapors depends upon its vapor pressure.
- The vaporization rate increases as the temperature increases. Therefore, flammable and combustible liquids are more hazardous at elevated temperatures than at room temperature.
Restrictions and guidelines: Because their vapors ignite and burn easily, flammable and combustible liquids have strict storage requirements. The hazard classification of a liquid determines the type and size of container in which it can be stored. For more information, see:
Hazard classifications: The National Fire Protection Association (NFPA) has established the following hazard classifications for flammable and combustible liquids:
| Hazard classification for flammable liquids |
| Class |
Flash point |
Boiling point |
Examples |
| I-A |
below 73°F (23°C) |
below 100°F (38°C) |
diethyl ether, pentane, ligroin, petroleum ether |
| I-B |
below 73°F (23°C) |
at or above 100°F (38°C) |
acetone, benzene, cyclohexane, ethanol |
| I-C |
73-100°F (24-38°C) |
---- |
p-xylene |
| Hazard classification for combustible liquids |
| II |
101-140°F (39-60°C) |
---- |
diesel fuel, motor oil, kerosene, cleaning solvents |
| III-A |
141-199°F (61-93°C) |
---- |
paints (oil base), linseed oil, mineral oil |
| III-B |
200°F (93°C) or above |
---- |
paints (oil base), neatsfoot oil |
Questions?
- If you are a research employee, contact the EH&S Research Assistance Program specialist assigned to your building.
- If you are a non-research employee, contact an EH&S general safety specialist, (858) 534-7513.
|